全文获取类型
收费全文 | 63150篇 |
免费 | 5624篇 |
国内免费 | 8380篇 |
专业分类
化学 | 44585篇 |
晶体学 | 2752篇 |
力学 | 1725篇 |
综合类 | 794篇 |
数学 | 8409篇 |
物理学 | 18889篇 |
出版年
2023年 | 628篇 |
2022年 | 995篇 |
2021年 | 1896篇 |
2020年 | 1692篇 |
2019年 | 1764篇 |
2018年 | 1500篇 |
2017年 | 1782篇 |
2016年 | 2314篇 |
2015年 | 2128篇 |
2014年 | 2821篇 |
2013年 | 5174篇 |
2012年 | 3452篇 |
2011年 | 3759篇 |
2010年 | 3297篇 |
2009年 | 4141篇 |
2008年 | 4100篇 |
2007年 | 4489篇 |
2006年 | 3803篇 |
2005年 | 2957篇 |
2004年 | 2798篇 |
2003年 | 2439篇 |
2002年 | 2053篇 |
2001年 | 1754篇 |
2000年 | 1389篇 |
1999年 | 1208篇 |
1998年 | 1063篇 |
1997年 | 945篇 |
1996年 | 1038篇 |
1995年 | 941篇 |
1994年 | 915篇 |
1993年 | 839篇 |
1992年 | 811篇 |
1991年 | 558篇 |
1990年 | 405篇 |
1989年 | 325篇 |
1988年 | 360篇 |
1987年 | 288篇 |
1986年 | 267篇 |
1985年 | 392篇 |
1984年 | 300篇 |
1983年 | 184篇 |
1982年 | 360篇 |
1981年 | 508篇 |
1980年 | 448篇 |
1979年 | 493篇 |
1978年 | 381篇 |
1977年 | 288篇 |
1976年 | 254篇 |
1974年 | 78篇 |
1973年 | 157篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
41.
The behaviors of ferromagnetic transition metals of the first period: Fe, Co and Ni are examined within density functional theory calculations in two dimensional carbon extended networks using model structure LiC6. Around geometry optimized structures, the energy-volume equations of states considering non magnetic and spin polarized configurations established ferromagnetic ground states with magnetizations –reduced with respect to the metals’– of 2 μB for FeC6 and 1 μB for CoC6 while no magnetic solution could be identified for NiC6. In the D6h point group of the P6/mmm space group lm decomposition of the d states results with increasing energy into doublet state E1g with d(x2-y2) and d(xy); singlet state A1g d(z2) and doublet state E2g d(xz) and d(yz) lying on EF and responsible of the onset of magnetic moments. This was mirrored via molecular orbital approach with a construct of Fe embedded between two extended carbon networks thus validating the model structure proposed for TC6 compounds. The 100% polarization in one spin channel allows proposing potential uses in spintronics applications. 相似文献
42.
X-ray imaging functionalization of biodegradable polyesters is a great demand and challenge in biomedical applications.In this work,a strategy of in-chain functionalization through the combination of ring opening copolymerization and oxime "Click" postfunctionalization was developed towards X-ray opaque polylactide copolymers.A functionalized cyclic carbonate was first synthesized and used as comonomer of polylactide copolymers,which were subjected to postfunctionalization of oxime "Click" reaction towards iodinated polylactide copolymers.The chemical structure and physical properties of the target products were traced and confirmed.In vitro cytotoxicity evaluation with 3T3-Swiss albino by Alamar blue demonstrated a low cytotoxicity.The X-ray radiopacity was analyzed by Micro-CT and quantified by Hounsfield Units value,which could be tailorable by the feedstock.It is a promising X-ray visible implantable biomaterial in biomedical applications. 相似文献
43.
Tomas Do Roman Guran Rea Jarosova Petra Ondrackova Zbysek Sladek Martin Faldyna Vojtech Adam Ondrej Zitka 《Molecules (Basel, Switzerland)》2020,25(23)
Respiratory infections are a real threat for humans, and therefore the pig model is of interest for studies. As one of a case for studies, Actinobacillus pleuropneumoniae (APP) caused infections and still worries many pig breeders around the world. To better understand the influence of pathogenic effect of APP on a respiratory system—lungs and tracheobronchial lymph nodes (TBLN), we aimed to employ matrix-assisted laser desorption/ionization time-of-flight mass spectrometry imaging (MALDI-TOF MSI). In this study, six pigs were intranasally infected by APP and two were used as non-infected control, and 48 cryosections have been obtained. MALDI-TOF MSI and immunohistochemistry (IHC) were used to study spatial distribution of infectious markers, especially interleukins, in cryosections of porcine tissues of lungs (necrotic area, marginal zone) and tracheobronchial lymph nodes (TBLN) from pigs infected by APP. CD163, interleukin 1β (IL-1β) and a protegrin-4 precursor were successfully detected based on their tryptic fragments. CD163 and IL-1β were confirmed also by IHC. The protegrin-4 precursor was identified by MALDI-TOF/TOF directly on the tissue cryosections. CD163, IL-1β and protegrin-4 precursor were all significantly (p < 0.001) more expressed in necrotic areas of lungs infected by APP than in marginal zone, TBLN and in control lungs. 相似文献
44.
Florio M. Ciaglia Fabio Di Cosmo Alberto Ibort Giuseppe Marmo 《Entropy (Basel, Switzerland)》2020,22(11)
The evolution of states of the composition of classical and quantum systems in the groupoid formalism for physical theories introduced recently is discussed. It is shown that the notion of a classical system, in the sense of Birkhoff and von Neumann, is equivalent, in the case of systems with a countable number of outputs, to a totally disconnected groupoid with Abelian von Neumann algebra. The impossibility of evolving a separable state of a composite system made up of a classical and a quantum one into an entangled state by means of a unitary evolution is proven in accordance with Raggio’s theorem, which is extended to include a new family of separable states corresponding to the composition of a system with a totally disconnected space of outcomes and a quantum one. 相似文献
45.
46.
Kalina Mambourg Laurie Bodart Nikolay Tumanov Steve Lanners Johan Wouters 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(3):205-211
The condensation reaction of 2‐mercapto‐3‐methoxybenzaldehyde with 3‐aminopyridine afforded an unexpected N‐alkylated [1,5]dithiocine instead of the N‐salicylideneaniline. The proposed mechanism for this condensation involves a strong intramolecular hydrogen bond between the thiol and the amine groups, leading to a second condensation. The corresponding product, i.e. 4,10‐dimethoxy‐13‐(pyridin‐3‐yl)‐6H,12H‐6,12‐epiminodibenzo[b,f][1,5]dithiocine methanol 0.463‐solvate, C21H18N2O2S2·0.463CH3OH, was characterized by single‐crystal X‐ray diffraction analysis. The supramolecular structure shows π–π stacking and S…S interactions in the crystal packing. Within the asymmetric unit, two geometries of the N atom are observed. Although a planar geometry should be expected, a pyramidal one is observed due to the crystal packing. The presence of the two geometries was further supported by density functional theory (DFT) calculations that show an electronic energy difference of less than 2 kJ mol?1 between the two conformers. 相似文献
47.
固体氧化物燃料电池的翘曲会影响电极-盖板界面的接触情况,从而影响电化学性能,对相关制造工艺提出了很大的挑战.为了分析燃料电池平面度对放电过程的影响,揭示其潜在的风险,我们建立了两个基于有限元法的仿真模型,对考虑平面度缺陷的燃料电池封装和放电进行分析.在对固体氧化物燃料电池进行平面度测量的基础上,首先建立了具有真实燃料电池翘曲特性的几何模型,分析封装过程中接触压力的分布情况.然后将接触电阻的仿真结果导入到三维多物理场耦合模型中,模拟具有平面度缺陷的燃料电池电化学性能.计算结果展示了燃料电池两侧封装过程中接触压力的分布情况.通过对比有接触电阻和无接触电阻的燃料电池电流密度,分析了电池与盖板的接触对放电过程的影响.结果表明,燃料电池的凹陷面较难达到满意的接触状态,需要比凸起面更大的封装压力.燃料电池表面接触电阻的变化将引起电流传导路径的变化,产生局部高电流或低电流.这项工作强调了在燃料电池中保持均匀分布的接触电阻的重要性,为今后的优化工作奠定了基础. 相似文献
48.
We consider the random‐cluster model (RCM) on with parameters p∈(0,1) and q ≥ 1. This is a generalization of the standard bond percolation (with edges open independently with probability p) which is biased by a factor q raised to the number of connected components. We study the well‐known Fortuin‐Kasteleyn (FK)‐dynamics on this model where the update at an edge depends on the global geometry of the system unlike the Glauber heat‐bath dynamics for spin systems, and prove that for all small enough p (depending on the dimension) and any q>1, the FK‐dynamics exhibits the cutoff phenomenon at with a window size , where λ∞ is the large n limit of the spectral gap of the process. Our proof extends the information percolation framework of Lubetzky and Sly to the RCM and also relies on the arguments of Blanca and Sinclair who proved a sharp mixing time bound for the planar version. A key aspect of our proof is the analysis of the effect of a sequence of dependent (across time) Bernoulli percolations extracted from the graphical construction of the dynamics, on how information propagates. 相似文献
49.
Z. Hadjou Bélaid S. Ben Mansour D. Boroguiaa A. Boubris L. Benhabib F. Z. Benkhaled 《Journal of Macromolecular Science: Physics》2020,59(11):686-696
AbstractThis work examines the development and characterization of tripropylene glycol di-acrylate/liquid crystal E7 (TPGDA/LC E7) PDLCs composite materials (polymer-dispersed-liquid-crystals). These systems were produced by UV irradiation photopolymerization (PIPS) of a mixture of the monomer tripropylene glycol di-acrylate (TPGDA) and the liquid crystal E7 (LC E7, a mixture of three cyano-biphenyl and one cyano-terphenyl LCs), in the presence of 2?wt% (of the acrylate/E7 mixture) of a photoinitiator. Electro-optical, thermal and optical characterization was used to understand the effect of the LC concentration on the electro-optical and thermo-physical properties of these materials. Polarizing optical microscopy (POM) and differential scanning calorimetry (DSC) studies were performed to observe the system morphology and to determine the transition temperatures of these materials, both as a function of their composition. The findings showed a slight variation of the nematic-isotropic transition temperature, TNI, of the LC E7 and of the glass transition temperature, Tg, of the TPGDA polymeric matrix as a function of the mass percentage of the LC E7. A very good electro-optical response for the composition 30/70?wt % TPGDA/LC E7 was obtained. 相似文献
50.
Zhen Song Dandan Zhou Quanlin Liu 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(3):311-311
An error in an equation in the paper by Song et al. [ Acta Cryst. (2019), C 75 , 1353–1358 ] is corrected. 相似文献